catena-Poly[(acetatochloridozinc)-μ-1,1′-[1,4-phenylenebis(methylene)]di-1H-imidazole]
نویسنده
چکیده
The title compound, [Zn(CH(3)CO(2))Cl(C(14)H(14)N(4))](n), is a one-dimensional coordination polymer in which the Zn(II) ion is tetrahedrally -coordinated by two N atoms of a bridging 1,1'-[1,4-phenyl-enebis(methyl-ene)]di-1H-imidazole ligand, an acetate O atom and a Cl atom. The Cl atom, two acetate O atoms and two acetate C atoms are located on a mirror plane. The coordination of the diimidazole ligand to the Zn(II) ion gives an infinite one-dimensional zigzag structure along the b-axis direction with the charge balanced by the chloride and acetate ions.
منابع مشابه
catena-Poly[[[aquasilver(I)]-μ-1,1′-(butane-1,4-diyl)di-1H-imidazole-κ2 N 3:N 3′] hemi(biphenyl-4,4′-dicarboxylate) dihydrate]
In the title compound, {[Ag(C(10)H(14)N(4))(H(2)O)](C(14)H(8)O(4))(0.5)·2H(2)O}(n), the Ag(I) ion is three-coordinated by two N atoms from two independent 1,1'-(butane-1,4-di-yl)di-1H-imidazole (BBI) ligands and one water O atom in a distorted T-shaped coordination geometry. The biphenyl-4,4'-dicarboxyl-ate (BPDC) dianions do not coordinate to Ag(I) ions but act as counter-ions. The Ag(I) ions ...
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In the title compound, [Co(C20H12O6)(C18H18N4)] n , the Co(II) atom, located on a twofold rotation axis, is hexa-coordinated to four O from two bis-bidentate 4,4'-[phenyl-enebis(-oxy)]dibenzoate (L) ligands and two N atoms from two 1,1'-(butane-1,4-di-yl)bis-(1H-benzimidazole) (bbbm) ligands, forming a distorted octahedral cis-N2O4 coordination environment. Polymeric zigzag chains along [102] a...
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The asymmetric unit of the title compound, {[Zn(C₁₆H₁₆O₄Si)(C₁₂H₁₀N₄)]·H(2)O}(n), consists of one Zn(II) ion, two half 3,3'-(dimethyl-silanedi-yl)dibenzoate ligands and two half 1,1'-(1,4-phenyl-ene)di-1H-imidazole ligands. The Zn(II) ion is four-coordinated by two O atoms from two carboxlate ligands, two N atoms from two imidazole ligands. Two Zn(II) ions are bridged by two carboxyl-ate groups...
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عنوان ژورنال:
دوره 69 شماره
صفحات -
تاریخ انتشار 2013